Ligand-based solid solution approach to stabilisation of sulphonic acid groups in porous coordination polymer Zr6O4(OH)4(BDC)6 (UiO-66).

نویسندگان

  • Maw Lin Foo
  • Satoshi Horike
  • Tomohiro Fukushima
  • Yuh Hijikata
  • Yoshiki Kubota
  • Masaki Takata
  • Susumu Kitagawa
چکیده

By adopting a ligand-based solid solution approach, the sulphonic acid functional group can be successfully incorporated into a porous coordination polymer with UiO-66 structure type. Zr(6)O(4)(OH)(4)(BDC-SO(3)H)(1.1)(BDC)(4.9) possesses enhanced heat of adsorption for carbon dioxide and acetone compared to Zr(6)O(4)(OH)(4)(BDC)(6).

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عنوان ژورنال:
  • Dalton transactions

دوره 41 45  شماره 

صفحات  -

تاریخ انتشار 2012